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020 ▼a 9780438090842
035 ▼a (MiAaPQ)AAI10871304
035 ▼a (MiAaPQ)OhioLINK:osu1492448144094887
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 247004
0820 ▼a 547
1001 ▼a Click, Kevin Andrew.
24510 ▼a Design and Synthesis of Organic Dyes for Solar Energy Conversion and Storage.
260 ▼a [S.l.]: ▼b The Ohio State University., ▼c 2017.
260 1 ▼a Ann Arbor: ▼b ProQuest Dissertations & Theses, ▼c 2017.
300 ▼a 226 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
500 ▼a Adviser: Yiying Wu.
5021 ▼a Thesis (Ph.D.)--The Ohio State University, 2017.
520 ▼a Solar energy is undoubtedly the most abundant source of renewable energy. Thus far, solar cell technologies have been limited from wide spread use due to their high material and fabrication costs. Dye sensitized solar cells (DSSCs) are an attrac
520 ▼a Also, DSSCs can be modified into solar driven water splitting dye sensitized photoelectrochemical cells (DSPECs). DSPECs are similar to DSSCs and have all the same advantages of cost, fabrication and tunability, but offer more practicality. Rath
520 ▼a An introduction is presented in Chapter 1 that describes the basic working principles and operation of DSSCs. A summary of the relevant literature is presented for each component of the p-type DSSC. Then the scope and goals of this dissertation
520 ▼a Chapter 2 introduces a novel "double acceptor" dye design principle when the core structure of a triphenylamine (TPA) donor is used in donor-pi-acceptor dyes for either application in n-type or p-type DSSCs. A series of novel double acceptor dye
520 ▼a Chapter 3 exploits the unique highly hydrophobic and large light absorption properties of the BH4 dye to answer the stability and wettability issues faced in solar driven water splitting applications. The unprecedented stability of the BH4 dye o
520 ▼a Chapter 4 further utilizes the aqueous stability of the BH series dyes for aqueous based DSSCs. Utilizing water as the electrolyte solvent makes the already cost effective tandem DSSCs even more economical and environmentally friendly. The BH2 d
520 ▼a Chapter 5 introduces a new dye (KC2) designed specifically for aqueous based dye sensitized electrodes. From what was learned in Chapters 2--4, there exists a dilemma between aqueous dye stability and wettability in the form of hydrophobicity. A
520 ▼a Chapter 6 summarizes the common experimental procedures and details used throughout the dissertation. More specific procedures relevant to each chapter are discussed in each corresponding chapter introduction.
590 ▼a School code: 0168.
650 4 ▼a Organic chemistry.
690 ▼a 0490
71020 ▼a The Ohio State University. ▼b Chemistry.
7730 ▼t Dissertation Abstracts International ▼g 79-10B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0168
791 ▼a Ph.D.
792 ▼a 2017
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T15000192 ▼n KERIS ▼z 이 자료의 원문은 한국교육학술정보원에서 제공합니다.
980 ▼a 201812 ▼f 2019
990 ▼a ***1012033