MARC보기
LDR02108nam u200421 4500
001000000419513
00520190215163733
008181129s2018 |||||||||||||||||c||eng d
020 ▼a 9780438353596
035 ▼a (MiAaPQ)AAI10841168
035 ▼a (MiAaPQ)umn:19473
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 247004
0820 ▼a 540
1001 ▼a Fan, Yang.
24510 ▼a Electrostatically Enhanced Thioureas: Synthesis, Reactivity and Selectivity.
260 ▼a [S.l.]: ▼b University of Minnesota., ▼c 2018.
260 1 ▼a Ann Arbor: ▼b ProQuest Dissertations & Theses, ▼c 2018.
300 ▼a 207 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
500 ▼a Adviser: Steven R. Kass.
5021 ▼a Thesis (Ph.D.)--University of Minnesota, 2018.
520 ▼a Hydrogen bonding exhibits its importance in enzyme-catalyzed chemical transformations, naturally occurring three-dimensional architectures and molecular recognition. In recent years, synthetic chemists have successfully exploited hydrogen bonds
520 ▼a Thiourea derivatives are among the most common and widely-developed hydrogen bond catalysts. Impressive results in terms of both yields and enantioselectivities in asymmetric syntheses have been obtained. A key feature in their success is the ab
520 ▼a The work described in this thesis focuses on the development of a class of positively charged acidity-enhanced thiourea catalysts which make use of an alkylated pyridinium substituent and an appropriate non-coordinating counteranion to enhance t
590 ▼a School code: 0130.
650 4 ▼a Chemistry.
650 4 ▼a Organic chemistry.
690 ▼a 0485
690 ▼a 0490
71020 ▼a University of Minnesota. ▼b Chemistry.
7730 ▼t Dissertation Abstracts International ▼g 80-01B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0130
791 ▼a Ph.D.
792 ▼a 2018
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T14999772 ▼n KERIS ▼z 이 자료의 원문은 한국교육학술정보원에서 제공합니다.
980 ▼a 201812 ▼f 2019
990 ▼a ***1012033