| LDR | | 02375nam u200433 4500 |
| 001 | | 000000419556 |
| 005 | | 20190215163754 |
| 008 | | 181129s2016 |||||||||||||||||c||eng d |
| 020 | |
▼a 9780438136229 |
| 035 | |
▼a (MiAaPQ)AAI10903797 |
| 040 | |
▼a MiAaPQ
▼c MiAaPQ
▼d 247004 |
| 082 | 0 |
▼a 540 |
| 100 | 1 |
▼a Zhao, Wei. |
| 245 | 10 |
▼a Efforts Toward Catalytic Methods Based on P(III)/P(V) Redox Cycling. |
| 260 | |
▼a [S.l.]:
▼b The Pennsylvania State University.,
▼c 2016. |
| 260 | 1 |
▼a Ann Arbor:
▼b ProQuest Dissertations & Theses,
▼c 2016. |
| 300 | |
▼a 341 p. |
| 500 | |
▼a Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B. |
| 502 | 1 |
▼a Thesis (Ph.D.)--The Pennsylvania State University, 2016. |
| 520 | |
▼a This dissertation describes efforts in the development of catalytic methods that are based on P(III)/P(V) redox cycling. Specifically, a catalytic oxygen atom transfer operating on P(III)/P(V)=O redox cycling and a reversible strong bond activat |
| 520 | |
▼a Part I of the dissertation is focused on the development of a new type of phosphorus(III)-mediated carbonyl functionalization via the condensation of electron-deficient carbonyl compounds and nucleophilic trivalent phosphorus compounds (aka the |
| 520 | |
▼a Part II of the dissertation extends the study on the effect of molecular geometry on reactivity. Through the design and synthesis of a new type of bicyclic phosphorous triamides with lower symmetry than canonical trivalent phosphorus compounds, |
| 520 | |
▼a In pursuing catalysis based on P(III)/P(V) redox cycling, we have illustrated the power of alternating reactivity via manipulating molecular geometry on both kinetic and thermodynamic terms. The strategy of molecular geometric distortion in the |
| 590 | |
▼a School code: 0176. |
| 650 | 4 |
▼a Chemistry. |
| 650 | 4 |
▼a Inorganic chemistry. |
| 650 | 4 |
▼a Organic chemistry. |
| 690 | |
▼a 0485 |
| 690 | |
▼a 0488 |
| 690 | |
▼a 0490 |
| 710 | 20 |
▼a The Pennsylvania State University.
▼b Chemistry. |
| 773 | 0 |
▼t Dissertation Abstracts International
▼g 79-12B(E). |
| 773 | |
▼t Dissertation Abstract International |
| 790 | |
▼a 0176 |
| 791 | |
▼a Ph.D. |
| 792 | |
▼a 2016 |
| 793 | |
▼a English |
| 856 | 40 |
▼u http://www.riss.kr/pdu/ddodLink.do?id=T15000753
▼n KERIS
▼z 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
| 980 | |
▼a 201812
▼f 2019 |
| 990 | |
▼a ***1012033 |