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008181129s2018 |||||||||||||||||c||eng d
020 ▼a 9780438384545
035 ▼a (MiAaPQ)AAI10931905
035 ▼a (MiAaPQ)columbia:14873
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 247004
0820 ▼a 547
1001 ▼a Radtke, Mark Alexander.
24510 ▼a Synthesis and Reactivity of Highly Stabilized Cyclopentadienes.
260 ▼a [S.l.]: ▼b Columbia University., ▼c 2018.
260 1 ▼a Ann Arbor: ▼b ProQuest Dissertations & Theses, ▼c 2018.
300 ▼a 164 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 80-02(E), Section: B.
500 ▼a Adviser: Tristan H. Lambert.
5021 ▼a Thesis (Ph.D.)--Columbia University, 2018.
520 ▼a This dissertation focuses on the development of cyclopentadienes as an emerging class of compounds for use in catalysis. Previous work in the Lambert group had established pentacarboxycyclopentadienes (PCCPs) as a promising class of Bronsted aci
520 ▼a Initial efforts were focused on the synthesis of leading to the development of two complementary methods for their synthesis. Chapter 2 details the improvements made to the transesterification of penta(methoxycarbonyl)cyclopentadiene, which allo
520 ▼a The second half of the dissertation examines the use of electrophilic silicon reagents and their use as Lewis acids. Given our ability to access highly electron-deficient cyclopentadienes, the silyl cyclopentadienes were targeted as potential Le
590 ▼a School code: 0054.
650 4 ▼a Organic chemistry.
650 4 ▼a Chemistry.
690 ▼a 0490
690 ▼a 0485
71020 ▼a Columbia University. ▼b Chemistry.
7730 ▼t Dissertation Abstracts International ▼g 80-02B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0054
791 ▼a Ph.D.
792 ▼a 2018
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T15001065 ▼n KERIS ▼z 이 자료의 원문은 한국교육학술정보원에서 제공합니다.
980 ▼a 201812 ▼f 2019
990 ▼a ***1012033