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020 ▼a 9780438126848
035 ▼a (MiAaPQ)AAI10903078
035 ▼a (MiAaPQ)umichrackham:001211
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 247004
0820 ▼a 628
1001 ▼a Gebarski, Benjamin Bartholomew.
24514 ▼a The Electronic and Atomic Structure of Actinide Contaminants at the Mineral-Fluid Interface.
260 ▼a [S.l.]: ▼b University of Michigan., ▼c 2018.
260 1 ▼a Ann Arbor: ▼b ProQuest Dissertations & Theses, ▼c 2018.
300 ▼a 175 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
500 ▼a Adviser: Udo Becker.
5021 ▼a Thesis (Ph.D.)--University of Michigan, 2018.
520 ▼a Geochemical reactions at the mineral-water interface are a critical factor in the mobility of actinide contaminants such as those intrinsic to nuclear waste storage facilities. Actinides can undergo a number of sorption, phase, and oxidation sta
520 ▼a In reducing conditions, soluble uranyl(VI) (UO22+) can be reduced to insoluble U(IV)O2 solid, resulting in the decrease of its mobility within the environment. Chapter 2 is an electrochemical investigation of U(VI) redox interactions in a relati
520 ▼a Actinide contaminants such as uranyl peroxides can also be immobilized via redox or adsorption reactions catalyzed by mineral surfaces. Therefore Chapter 3 uses electrochemical atomic force microscopy (EC-AFM) in conjunction with spectroscopic m
520 ▼a Actinides exceptionally mobile in aqueous conditions, such as pentavalent plutonyl (PuO2+), can be immobilized without a change in oxidation state via adsorption or incorporation into mineral hosts. Thus, Chapter 4 is a theoretical investigation
590 ▼a School code: 0127.
650 4 ▼a Environmental science.
690 ▼a 0768
71020 ▼a University of Michigan. ▼b Earth and Environmental Sciences.
7730 ▼t Dissertation Abstracts International ▼g 79-12B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0127
791 ▼a Ph.D.
792 ▼a 2018
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T15000574 ▼n KERIS ▼z 이 자료의 원문은 한국교육학술정보원에서 제공합니다.
980 ▼a 201812 ▼f 2019
990 ▼a ***1012033