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020 ▼a 9780438136113
035 ▼a (MiAaPQ)AAI10903786
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 247004
0820 ▼a 631.4
1001 ▼a Woodward, Emily E.
24510 ▼a Optimization of Estrogen Analyses and Quantification of Environmental Samples from Pennsylvania Water Systems.
260 ▼a [S.l.]: ▼b The Pennsylvania State University., ▼c 2016.
260 1 ▼a Ann Arbor: ▼b ProQuest Dissertations & Theses, ▼c 2016.
300 ▼a 188 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
5021 ▼a Thesis (Ph.D.)--The Pennsylvania State University, 2016.
520 ▼a The increase in the presence of pharmaceuticals and endocrine disrupting hormones (EDCs) in the environment has had a direct impact on aquatic organisms in the environment. Estrogen hormones, one class of EDCs, have been quantified in natural so
520 ▼a The goals of this dissertation were to (1) determine an optimal estrogen extraction solvent that yielded the largest E1, E2, and EE2 recovery percentages, (2) optimize separation of ten estrogen and estrogenic compounds using different stationar
520 ▼a For the first objective, four organic solvents and three solid phase extraction (SPE) loading ratios were evaluated in order to determine an optimal method to extract estrogens from an agricultural soil (1.09 %TOC). Solvents used to extract the
520 ▼a For the second objective, standard solutions containing ten estrogenic compounds were separated using six different stationary phase and mobile phase combinations. Three stationary phases were evaluated, C18, biphenyl, and RP-Amide, and two mobi
520 ▼a For the third objective, results indicated that sorption varied between E1, E2, and EE2 and between the three soils studied. Partition coefficient values, Kd and Kf, increased with an increase in soil organic carbon concentration and vice versa,
520 ▼a Finally, E1, E2, and EE2 baseline data was established for the Penn State Living Filter wastewater irrigation site, and the Sinnemahoning Creek Watershed. At the Living Filter, all three compounds were detected in groundwater well samples. Howev
590 ▼a School code: 0176.
650 4 ▼a Soil sciences.
650 4 ▼a Chemistry.
650 4 ▼a Environmental science.
690 ▼a 0481
690 ▼a 0485
690 ▼a 0768
71020 ▼a The Pennsylvania State University. ▼b Soil Science and Biogeochemistry.
7730 ▼t Dissertation Abstracts International ▼g 79-12B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0176
791 ▼a Ph.D.
792 ▼a 2016
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T15000743 ▼n KERIS ▼z 이 자료의 원문은 한국교육학술정보원에서 제공합니다.
980 ▼a 201812 ▼f 2019
990 ▼a ***1012033