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020 ▼a 9780438310063
035 ▼a (MiAaPQ)AAI10970765
035 ▼a (MiAaPQ)OhioLINK:osu1461253897
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 247004
0820 ▼a 641
1001 ▼a Sigurdson, Gregory T.
24510 ▼a Evaluating the Effects of Anthocyanin Structure and the Role of Metal Ions on the Blue Color Evolution of Anthocyanins in Varied pH Environments.
260 ▼a [S.l.]: ▼b The Ohio State University., ▼c 2016.
260 1 ▼a Ann Arbor: ▼b ProQuest Dissertations & Theses, ▼c 2016.
300 ▼a 199 p.
500 ▼a Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
500 ▼a Adviser: M. Monica Giusti.
5021 ▼a Thesis (Ph.D.)--The Ohio State University, 2016.
520 ▼a Due to consumer demand and possible health concerns, the use of synthetic food colorants has been decreasing. Synthetic red and yellow colorants are most commonly used in the food industry
520 ▼a Acylated and nonacylated derivatives of cyanidin and delphinidin were combined with various metal ions (Mg2+, Al3+, Cr3+, Fe3+, and Ga3+) in factorial excesses to anthocyanin concentration (as large as 2000x [anthocyanin]) in pH 3-8. Phenolic ac
520 ▼a Anthocyanin responses to metal ion chelation were dependent on all factors tested. In all pH, anthocyanins exhibited bathochromic and hyperchromic shifts becoming more purple and blue. Largest bathochromic shifts occurred in pH 6, and largest hy
520 ▼a Metal chelation resulted in larger bathochromic shifts on anthocyanins with more B-ring hydroxyl groups (delphinidin > cyanidin). Anthocyanins lacking acylation typically underwent much larger bathochromic shifts
520 ▼a Bivalent Mg2+ showed no obvious effect on anthocyanin color. Generally, bathochromic shifts on anthocyanin were greatest with more electron rich metal ions: Fe3+ . Ga3+ > Al 3+ > Cr3+.
520 ▼a Metal chelation by anthocyanins resulted in blue and purple hues similar to currently used synthetic colorants in pH environments where these colors are not typically expressed, further indicating potential to act as alternatives.
590 ▼a School code: 0168.
650 4 ▼a Food science.
650 4 ▼a Organic chemistry.
690 ▼a 0359
690 ▼a 0490
71020 ▼a The Ohio State University. ▼b Food Science and Technology.
7730 ▼t Dissertation Abstracts International ▼g 80-01B(E).
773 ▼t Dissertation Abstract International
790 ▼a 0168
791 ▼a Ph.D.
792 ▼a 2016
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T15001355 ▼n KERIS ▼z 이 자료의 원문은 한국교육학술정보원에서 제공합니다.
980 ▼a 201812 ▼f 2019
990 ▼a ***1012033