| LDR | | 00000nam u2200205 4500 |
| 001 | | 000000432067 |
| 005 | | 20200224113235 |
| 008 | | 200131s2019 ||||||||||||||||| ||eng d |
| 020 | |
▼a 9781085679114 |
| 035 | |
▼a (MiAaPQ)AAI13898636 |
| 040 | |
▼a MiAaPQ
▼c MiAaPQ
▼d 247004 |
| 082 | 0 |
▼a 547 |
| 100 | 1 |
▼a McConnell, Cameron Reed. |
| 245 | 10 |
▼a Leveraging 1,2-Azaborine's Distinct Electronic Structure to Access New Building Blocks. |
| 260 | |
▼a [S.l.]:
▼b Boston College.,
▼c 2019. |
| 260 | 1 |
▼a Ann Arbor:
▼b ProQuest Dissertations & Theses,
▼c 2019. |
| 300 | |
▼a 325 p. |
| 500 | |
▼a Source: Dissertations Abstracts International, Volume: 81-03, Section: B. |
| 500 | |
▼a Advisor: Liu, Shih-Yuan. |
| 502 | 1 |
▼a Thesis (Ph.D.)--Boston College, 2019. |
| 506 | |
▼a This item must not be sold to any third party vendors. |
| 520 | |
▼a Described herein are three projects that derive from in-depth studies of the distinct electronic structure of monocyclic 1,2-dihydro-1,2-azaborine (heretofore referred to as simply 1,2-azaborine). In the first chapter, the first comprehensive review of the late-stage functionalization methods available for 1,2-azaborines as well as their bicyclic and polycyclic (BN-PAH) counterparts is presented. In the second chapter, the development of a general method for both C4 and C5 functionalization based on the building block approach is described. The distinct electronic structure of 1,2-azaborine enables the chemical separation and further functionalization of C4 and C5 borylated isomers. In the second part, the C4, C5, and C6 isomers of BN-styrene analogues were prepared using the newly developed azaborine building blocks. The corresponding polymers were synthesized and extensively characterized in order to compare the effects of the BN-bond positioning relative to the polymer chain. In the fourth and final chapter, 1,2-azaborine-containing phosphine ligands featuring a P-B bond are synthesized. A comparative electronic structure analysis is performed between the BN-phosphine ligands and their direct all-carbon counterparts. |
| 590 | |
▼a School code: 0016. |
| 650 | 4 |
▼a Organic chemistry. |
| 690 | |
▼a 0490 |
| 710 | 20 |
▼a Boston College.
▼b GSAS - Chemistry. |
| 773 | 0 |
▼t Dissertations Abstracts International
▼g 81-03B. |
| 773 | |
▼t Dissertation Abstract International |
| 790 | |
▼a 0016 |
| 791 | |
▼a Ph.D. |
| 792 | |
▼a 2019 |
| 793 | |
▼a English |
| 856 | 40 |
▼u http://www.riss.kr/pdu/ddodLink.do?id=T15491961
▼n KERIS
▼z 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
| 980 | |
▼a 202002
▼f 2020 |
| 990 | |
▼a ***1008102 |
| 991 | |
▼a E-BOOK |