| LDR | | 00000nam u2200205 4500 |
| 001 | | 000000432242 |
| 005 | | 20200224115332 |
| 008 | | 200131s2019 ||||||||||||||||| ||eng d |
| 020 | |
▼a 9781088304853 |
| 035 | |
▼a (MiAaPQ)AAI13900153 |
| 040 | |
▼a MiAaPQ
▼c MiAaPQ
▼d 247004 |
| 082 | 0 |
▼a 540 |
| 100 | 1 |
▼a Nguyen, Julia. |
| 245 | 10 |
▼a Cross Coupling of Alkenyl Gold Complexes with Alkyl Electrophiles and Nickel Catalyzed Hydroarylation of Alkenes. |
| 260 | |
▼a [S.l.]:
▼b University of Washington.,
▼c 2019. |
| 260 | 1 |
▼a Ann Arbor:
▼b ProQuest Dissertations & Theses,
▼c 2019. |
| 300 | |
▼a 94 p. |
| 500 | |
▼a Source: Dissertations Abstracts International, Volume: 81-04, Section: B. |
| 500 | |
▼a Advisor: Lalic, Gojko. |
| 502 | 1 |
▼a Thesis (Ph.D.)--University of Washington, 2019. |
| 506 | |
▼a This item must not be sold to any third party vendors. |
| 506 | |
▼a This item must not be added to any third party search indexes. |
| 520 | |
▼a Transition metal catalysis is a powerful strategy for the construction of organic molecules. The development of novel methods in this field can help improve the speed and efficiency with which we synthesize complex organic molecules and broaden the scope of accessible products. Here we describe the development of two reactions involving transition metals. The first is a cross-coupling reaction between alkenyl gold and alkyl triflates, resulting in the formation of a new C-C bond. While several strategies are known that enable 慣-selective cross-coupling of alkenyl gold complexes, we are able to achieve 棺-selective cross-coupling by taking advantage of an alternative mode of reactivity. The second reaction described is a nickel catalyzed hydroarylation of alkenes. We are able to achieve good anti-Markovnikov selectivity with a wide range of alkenes, including styrenes, alkyl substituted alkenes, and enol ethers. |
| 590 | |
▼a School code: 0250. |
| 650 | 4 |
▼a Chemistry. |
| 650 | 4 |
▼a Metals. |
| 650 | 4 |
▼a Catalysis. |
| 650 | 4 |
▼a Chemical reactions. |
| 690 | |
▼a 0485 |
| 710 | 20 |
▼a University of Washington.
▼b Chemistry. |
| 773 | 0 |
▼t Dissertations Abstracts International
▼g 81-04B. |
| 773 | |
▼t Dissertation Abstract International |
| 790 | |
▼a 0250 |
| 791 | |
▼a Ph.D. |
| 792 | |
▼a 2019 |
| 793 | |
▼a English |
| 856 | 40 |
▼u http://www.riss.kr/pdu/ddodLink.do?id=T15492151
▼n KERIS
▼z 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
| 980 | |
▼a 202002
▼f 2020 |
| 990 | |
▼a ***1008102 |
| 991 | |
▼a E-BOOK |