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020 ▼a 9781085607001
035 ▼a (MiAaPQ)AAI13886217
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 247004
0820 ▼a 551
1001 ▼a Nicewonger, Melinda Renee.
24510 ▼a Ice Core Records of Ethane and Acetylene for Use as Biomass Burning Proxies.
260 ▼a [S.l.]: ▼b University of California, Irvine., ▼c 2019.
260 1 ▼a Ann Arbor: ▼b ProQuest Dissertations & Theses, ▼c 2019.
300 ▼a 208 p.
500 ▼a Source: Dissertations Abstracts International, Volume: 81-02, Section: B.
500 ▼a Advisor: Saltzman, Eric S.
5021 ▼a Thesis (Ph.D.)--University of California, Irvine, 2019.
506 ▼a This item must not be sold to any third party vendors.
520 ▼a Biomass burning plays a major role in atmospheric chemistry, carbon cycling, and climate. To understand and better predict how biomass burning may change in the future, it is important to investigate how biomass burning has varied in the past. Proxy records of biomass burning over long time periods are necessary to identify the link between biomass burning and climate. This information is needed by Earth system models to make accurate projections about future climate change and biomass burning. In this dissertation, new ice core measurements are used to reconstruct biomass burning variability over the last 2,000 years. The trace gases ethane and acetylene are released to the atmosphere during biomass burning events. New analytical techniques utilizing a wet-extraction method coupled with gas-chromatography and high-resolution mass spectrometry analysis were developed to measure these gases in polar ice cores. The abundance of ethane and acetylene were measured in ice cores from Summit, Greenland, West Antarctic Ice Sheet (WAIS) Divide, Antarctica, and South Pole, Antarctica. The ice core ethane and acetylene records exhibit similar temporal variability over the 2,000-year period. Over Greenland, little variability is observed in the ethane and acetylene levels. Over Antarctica, they both decline substainitally after 1500 CE, ethane by roughly 30% and acetylene by 50%. Using chemistry transport modeling, this decline in Antarctic ethane and acetylene was attributed to a decline in biomass burning emissions in the non-boreal (tropical) biome, rather than the boreal forests, from the warmer Medieval Period to the cooler Little Ice Age.My study presents the first millennial scale record of these trace gases in polar ice cores and demonstrates that long-term paleo-climate records from these reactive, trace-level gases are attainable. The results show spatial and temporal variability in biomass burning emissions which were likely driven by climate. More work is needed to extend these records further back in time to periods where there is less influence by human activity and where there is a broader range of climatic variation in order to fully tease apart and quantify the climatic, rather than human, controls over fire in order to aid in validation of Earth system models.
590 ▼a School code: 0030.
650 4 ▼a Atmospheric chemistry.
650 4 ▼a Biogeochemistry.
650 4 ▼a Paleoclimate science.
690 ▼a 0371
690 ▼a 0425
690 ▼a 0653
71020 ▼a University of California, Irvine. ▼b Earth System Science - Ph.D..
7730 ▼t Dissertations Abstracts International ▼g 81-02B.
773 ▼t Dissertation Abstract International
790 ▼a 0030
791 ▼a Ph.D.
792 ▼a 2019
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T15491497 ▼n KERIS ▼z 이 자료의 원문은 한국교육학술정보원에서 제공합니다.
980 ▼a 202002 ▼f 2020
990 ▼a ***1816162
991 ▼a E-BOOK