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020 ▼a 9781085673259
035 ▼a (MiAaPQ)AAI22617915
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 247004
0820 ▼a 540
1001 ▼a Dannatt, Jonathan E.
24510 ▼a Advancing Frontiers in Reactive and Selective Iridium C-H Borylation Catalysis and Targeted Silsesquioxane Synthesis.
260 ▼a [S.l.]: ▼b Michigan State University., ▼c 2019.
260 1 ▼a Ann Arbor: ▼b ProQuest Dissertations & Theses, ▼c 2019.
300 ▼a 521 p.
500 ▼a Source: Dissertations Abstracts International, Volume: 81-03, Section: B.
500 ▼a Advisor: Maleczka, Rob.
5021 ▼a Thesis (Ph.D.)--Michigan State University, 2019.
506 ▼a This item must not be sold to any third party vendors.
520 ▼a The studies in this dissertation are aimed at uncovering reactive and selective Ir-catalyzed C-H borylation (CHB) catalysts. Due to the high versatility of organoboron species, green methodology to produce the C-B bond is poised to support a myriad of subsequent transformations. These transformations include Suzuki couplings, aminations, oxidations, halogenations, cyanations, and trifluoromethylations.Typical iridium catalyzed CHBs proceed through an iridium trisboryl with a bidentate ligand such as bipyridine or 1,10-phenanthroline. The selectivity of these standard catalysts is generally driven by sterics
590 ▼a School code: 0128.
650 4 ▼a Organic chemistry.
650 4 ▼a Chemistry.
690 ▼a 0490
690 ▼a 0485
71020 ▼a Michigan State University. ▼b Chemistry - Doctor of Philosophy.
7730 ▼t Dissertations Abstracts International ▼g 81-03B.
773 ▼t Dissertation Abstract International
790 ▼a 0128
791 ▼a Ph.D.
792 ▼a 2019
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T15493503 ▼n KERIS ▼z 이 자료의 원문은 한국교육학술정보원에서 제공합니다.
980 ▼a 202002 ▼f 2020
990 ▼a ***1008102
991 ▼a E-BOOK