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020 ▼a 9781687937520
035 ▼a (MiAaPQ)AAI22623400
040 ▼a MiAaPQ ▼c MiAaPQ ▼d 247004
0820 ▼a 541
1001 ▼a Beasley, Madeleine S.
24510 ▼a In situ Characterization of Vapor-Deposited Organic Glasses.
260 ▼a [S.l.]: ▼b The University of Wisconsin - Madison., ▼c 2019.
260 1 ▼a Ann Arbor: ▼b ProQuest Dissertations & Theses, ▼c 2019.
300 ▼a 290 p.
500 ▼a Source: Dissertations Abstracts International, Volume: 81-04, Section: B.
500 ▼a Advisor: Ediger, Mark.
5021 ▼a Thesis (Ph.D.)--The University of Wisconsin - Madison, 2019.
506 ▼a This item must not be sold to any third party vendors.
520 ▼a Vapor-deposited organic glasses are used in a variety of applications, ranging from pharmaceuticals with high bioavailability to the active material for charge mobility in layers of organic light emitting diodes. The glasses studied by the Ediger group are prepared by physical vapor deposition. Depending on the substrate temperature, the as-prepared glasses can have a range of extraordinary properties including high kinetic stability, high density, and suppressed secondary relaxations relative to a glass prepared in the traditional manner of liquid cooling. The work in this thesis focuses on simple organic molecules that serve as model systems for understanding these extraordinary properties that vapor-deposited glasses can have. Specifically, the ability of a series of trialkyl phosphates to form kinetically stable glasses, the proximity of vapor-deposited ethylbenzene glasses to the "ideal glass" state, and physical vapor deposition of the polyamorphic system triphenyl phosphite is described.
590 ▼a School code: 0262.
650 4 ▼a Chemistry.
650 4 ▼a Physical chemistry.
690 ▼a 0485
690 ▼a 0494
71020 ▼a The University of Wisconsin - Madison. ▼b Chemistry.
7730 ▼t Dissertations Abstracts International ▼g 81-04B.
773 ▼t Dissertation Abstract International
790 ▼a 0262
791 ▼a Ph.D.
792 ▼a 2019
793 ▼a English
85640 ▼u http://www.riss.kr/pdu/ddodLink.do?id=T15493993 ▼n KERIS ▼z 이 자료의 원문은 한국교육학술정보원에서 제공합니다.
980 ▼a 202002 ▼f 2020
990 ▼a ***1008102
991 ▼a E-BOOK