LDR | | 00000nam u2200205 4500 |
001 | | 000000434832 |
005 | | 20200227105851 |
008 | | 200131s2019 ||||||||||||||||| ||eng d |
020 | |
▼a 9781085753609 |
035 | |
▼a (MiAaPQ)AAI22620327 |
040 | |
▼a MiAaPQ
▼c MiAaPQ
▼d 247004 |
082 | 0 |
▼a 540 |
100 | 1 |
▼a Shannon, Timothy Michael. |
245 | 10 |
▼a Selective Synthesis of Aromatic and Saturated Organoboron Compounds. |
260 | |
▼a [S.l.]:
▼b Michigan State University.,
▼c 2019. |
260 | 1 |
▼a Ann Arbor:
▼b ProQuest Dissertations & Theses,
▼c 2019. |
300 | |
▼a 300 p. |
500 | |
▼a Source: Dissertations Abstracts International, Volume: 81-03, Section: B. |
500 | |
▼a Advisor: Smith, Milton R., III. |
502 | 1 |
▼a Thesis (Ph.D.)--Michigan State University, 2019. |
506 | |
▼a This item must not be sold to any third party vendors. |
506 | |
▼a This item must not be added to any third party search indexes. |
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▼a C-H borylation (CHB) is a method to functionalize C-H bonds. The development of CHB has taken many years but is getting to the point of well-established chemistry. The directed CHB is possible for a variety of differing substrates and differing loctions of direction. A new method for ortho directed CHB of esters amides and ketones was developed through the use of pyridine based monodentate ligands.Using 4-cyano-2-methoxypyridine as a ligand iridium catalyzed CHB of esters ketones and amides were performed. The mechanism of CHB in this process likely operates through a different rate-determining step than the other C-H borylation methods used as it was found that the kinetic isotope effect data did not clearly support C-H activation as rate-determining.The development of sp3 C-H borylation is not as advanced as sp2 CHB |
590 | |
▼a School code: 0128. |
650 | 4 |
▼a Chemistry. |
690 | |
▼a 0485 |
710 | 20 |
▼a Michigan State University.
▼b Chemistry - Doctor of Philosophy. |
773 | 0 |
▼t Dissertations Abstracts International
▼g 81-03B. |
773 | |
▼t Dissertation Abstract International |
790 | |
▼a 0128 |
791 | |
▼a Ph.D. |
792 | |
▼a 2019 |
793 | |
▼a English |
856 | 40 |
▼u http://www.riss.kr/pdu/ddodLink.do?id=T15493711
▼n KERIS
▼z 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
980 | |
▼a 202002
▼f 2020 |
990 | |
▼a ***1008102 |
991 | |
▼a E-BOOK |