목차
Chapter 01 서론 ... 1
Chapter 02 고분자의 역사 ... 11
Chapter 03 천연 고분자와 합성 고분자 ... 19
3.1 천연 고분자 ... 21
3.2 합성 고분자 ... 23
Chapter 04 용어 정리 ... 25
4.1 Monomers(단량체) ... 27
4.2 Dimers, Trimers, and Oligomers ... 27
4.3 Polymers(고분자) ... 28
4.4 Thermoplastic(열가소성) ... 35
4.5 Thermoset(열경화성) ... 37
4.6 Elastomer(탄성체) ... 37
4.7 Palsticizer(가소제) ... 38
4.8 Polymer Blend(고분자 블렌드) ... 40
4.9 Tacticity ... 42
Chapter 05 몇 가지 중합 공정(polymerization process) ... 45
5.1 step-reaction polymerization ... 49
5.2 Chain-reaction polymerization(사슬 중합 반응) ... 52
Chapter 06 Nomenclature(명명법) ... 55
6.1 Vinyl Polymers ... 57
6.2 Vinyl Copolymers ... 62
6.3 Nonvinyl polymers ... 63
6.4 Nonvinyl Copolymers ... 66
6.5 End Groups ... 67
6.6 약어(abbreviations) ... 67
Chapter 07 산업용 고분자 ... 71
7.1 plastic ... 73
7.2 Fiber ... 75
7.3 Rubber(Elastomer) ... 76
7.4 Coatings and Adhesives ... 77
Chapter 08 고분자의 재활용 ... 79
Chapter 09 고분자 관련 서적과 잡지들 ... 83
9.1 Textbooks ... 85
9.2 Encyclopedias and Yearbooks ... 86
9.3 Handbooks ... 87
9.4 Continuing Series(연속 간행물) ... 90
9.5 Journals ... 91
9.6 Laboratory Experiments in Polymer Chemistry ... 96
Chapter 10 Polymer Morphology ... 99
10.1 Crystalline Polymers ... 104
10.2 Amorphous Polymers ... 104
10.3 Microcrystallinity ... 105
10.4 Crystallinity와 물리적인 성질 ... 108
10.5 Enhancement of Crystallinity ... 109
10.6 Crystallinity and Polymer Structure ... 110
10.7 Models of Crystallinity ... 111
10.8 Liquid Crystallinity(액정) ... 115
10.9 Secondary Forces ... 117
10.10 Orientation of Polymers(고분자의 방향성) ... 119
Chapter 11 GlassTransition(유리 전이) ... 121
11.1 The Glassy State ... 123
11.2 The Rubbery State ... 124
11.3 The Flexible, Nonelastomeric State ... 125
11.4 Change of Physical Properties at Glass Transition Temperature ... 126
11.5 Specific Volume ... 130
11.6 Enthalpy Change ... 134
11.7 Calorimetry(DSC와 DTA) ... 136
11.8 Factors influencing Tg ... 145
11.9 Glass transition temperature에서의 고분자 성질 ... 152
Chapter 12 Mechanical properties of polymers ... 155
12.1 Strength(강도) ... 158
12.2 Elongation(신장, 늘어남, 인장) ... 168
12.3 Modulus ... 170
12.4 Toughness(질김) ... 174
12.5 Mechanical properties of real polymers ... 178
Chapter 13 Molecular weight of polymers ... 181
13.1 Number average molecular weight() ... 185
13.2 Weight average molecular weight ... 187
13.3 End-group analysis ... 192
13.4 Gel permeation chromatography(GPC) ... 193
13.5 Light scattering measurements ... 203
13.6 Osmometry ... 217
13.7 Sedimentation(혹은 Ultracentrifugation) ... 221
13.8 Cryoscopy and ebulliometry ... 231
13.9 Viscometry ... 232
Chapter 14 Free radical (vinyl) Polymerization ... 249
14.1 Free radical process ... 253
14.2 Free radical initiators ... 261
14.3 Free radical polymerization과 관련된 문제점들 ... 267
14.4 Techniques of free radical polymerization ... 272
14.5 Kinetics of free radical polymerization ... 281
Chapter 15 Ionic polymerization ... 289
15.1 Cationic polymerization ... 293
15.2 Anionic polymerization ... 295
부록 ... 303
A. Polymer glossary(고분자 용어설명의 요약) ... 305
B. 고분자 실험 관련 journals ... 309
찾아보기 ... 319
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