자료유형 | 학위논문 |
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서명/저자사항 | The Apparent Kinetics of Hydrogen Production with Water-Slurred Aluminum Delivery in Aqueous Sodium Hydroxide Solutions. |
개인저자 | Noland, Brian Michael John. |
단체저자명 | University of California, Davis. Mechanical and Aeronautical Engineering. |
발행사항 | [S.l.]: University of California, Davis., 2019. |
발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2019. |
형태사항 | 239 p. |
기본자료 저록 | Dissertations Abstracts International 81-05B. Dissertation Abstract International |
ISBN | 9781392497289 |
학위논문주기 | Thesis (Ph.D.)--University of California, Davis, 2019. |
일반주기 |
Source: Dissertations Abstracts International, Volume: 81-05, Section: B.
Advisor: Erickson, Paul A. |
이용제한사항 | This item must not be sold to any third party vendors. |
요약 | A first experimental study of the effect on hydrogen production kinetics of aqueous slurry-based aluminum delivery applied to the alkaline corrosion reaction with aqueous sodium hydroxide was conducted. This thermodynamically spontaneous water-splitting reaction was investigated in the present work as a potential zero-emission hydrogen fuel source for portable or water-borne applications. Heterogeneous mass-action-Arrhenius type kinetic models were derived from 48 randomized factorial experiments employing a single continuously stirred temperature controlled reactor at near-ambient conditions which describe the effects of temperature Tr, micron-scale Al powder surface area S, and hydroxide concentration혻C under each of two Al powder delivery modes: initially air-dry, and initially hydrated in an aqueous slurry. The fitted model was of the initial H2 production rate of a reaction, &Vdot |
일반주제명 | Alternative energy. Chemical engineering. Statistics. |
언어 | 영어 |
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