자료유형 | 학위논문 |
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서명/저자사항 | Applications of Multivariate Raman Spectroscopy. |
개인저자 | Matt, Sarah M. |
단체저자명 | Purdue University. Chemistry. |
발행사항 | [S.l.]: Purdue University., 2018. |
발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2018. |
형태사항 | 120 p. |
기본자료 저록 | Dissertation Abstracts International 79-10B(E). Dissertation Abstract International |
ISBN | 9780438016972 |
학위논문주기 | Thesis (Ph.D.)--Purdue University, 2018. |
일반주기 |
Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
Adviser: Dor Ben-Amotz. |
요약 | The vibrational Raman spectrum of water can be used to probe changes in water structure as a function of temperature and due to solute-water interactions. We have demonstrated a diverse set of these applications by combining Raman spectroscopy w |
요약 | Next, we probed the water structure around select biological molecules as a function of temperature, pH and position within the molecule. These proteins, tripeptides and amino acids were challenging due to fluorescence interference and low aqueo |
요약 | Additionally, spectra obtained from both pure and isotopically dilute water were used to selectively probe the influence of intermolecular coupling on the OH (and OD) band shapes and intensities of H2O (and D 2O) in the absence of intramolecular |
요약 | Lastly, the temperature-dependent shape and intensity of the OH stretching band of the water spectrum enabled development of an SMCR-based Raman thermometry method. This method was applied to non-invasively measure the temperature of the fluid i |
일반주제명 | Physical chemistry. |
언어 | 영어 |
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