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Applications of Multivariate Raman Spectroscopy

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서명/저자사항Applications of Multivariate Raman Spectroscopy.
개인저자Matt, Sarah M.
단체저자명Purdue University. Chemistry.
발행사항[S.l.]: Purdue University., 2018.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2018.
형태사항120 p.
기본자료 저록Dissertation Abstracts International 79-10B(E).
Dissertation Abstract International
ISBN9780438016972
학위논문주기Thesis (Ph.D.)--Purdue University, 2018.
일반주기 Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
Adviser: Dor Ben-Amotz.
요약The vibrational Raman spectrum of water can be used to probe changes in water structure as a function of temperature and due to solute-water interactions. We have demonstrated a diverse set of these applications by combining Raman spectroscopy w
요약Next, we probed the water structure around select biological molecules as a function of temperature, pH and position within the molecule. These proteins, tripeptides and amino acids were challenging due to fluorescence interference and low aqueo
요약Additionally, spectra obtained from both pure and isotopically dilute water were used to selectively probe the influence of intermolecular coupling on the OH (and OD) band shapes and intensities of H2O (and D 2O) in the absence of intramolecular
요약Lastly, the temperature-dependent shape and intensity of the OH stretching band of the water spectrum enabled development of an SMCR-based Raman thermometry method. This method was applied to non-invasively measure the temperature of the fluid i
일반주제명Physical chemistry.
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