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Reagent-dictated Site Selective Hydrocarbon Functionalization Using Nitrogen-centered Radicals
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| 자료유형 | 학위논문 |
|---|---|
| 서명/저자사항 | Reagent-dictated Site Selective Hydrocarbon Functionalization Using Nitrogen-centered Radicals. |
| 개인저자 | Carestia, Anthony Michael. |
| 단체저자명 | The University of North Carolina at Chapel Hill. Chemistry. |
| 발행사항 | [S.l.]: The University of North Carolina at Chapel Hill., 2018. |
| 발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2018. |
| 형태사항 | 268 p. |
| 기본자료 저록 | Dissertation Abstracts International 80-01B(E). Dissertation Abstract International |
| ISBN | 9780438349681 |
| 학위논문주기 | Thesis (Ph.D.)--The University of North Carolina at Chapel Hill, 2018. |
| 일반주기 |
Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
Advisers: Erik J. Alexanian |
| 요약 | Chapter 1. Aliphatic C-H Functionalization: An overview of aliphatic radical C-H functionalization is presented with an emphasis on the challenge of site selectivity. Methods covered range from simple, unselective free radical halogenation to hi |
| 요약 | Chapter 2. Reagent-Dictated Site-Selective C-H Chlorination: The development of a site-selective C-H chlorination is discussed. Primary site selectivity is achieved using highly hindered N-chloroamide reagent used. A computational study of the g |
| 요약 | Chapter 3. Primary Selective C-H Functionalization of Polyolefins: A complementary method of polyolefin xanthylation was developed. The regioselectivity of the reaction favors 1° functionalization over 2° functionalization, in stark contrast to |
| 일반주제명 | Organic chemistry. Chemistry. |
| 언어 | 영어 |
| 바로가기 | 
: 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
