자료유형 | 학위논문 |
---|---|
서명/저자사항 | Diverse Reactivity of Bimetallic Nickel Imido Complexes Supported by a Redox-active Ligand. |
개인저자 | Powers, Ian G. |
단체저자명 | Purdue University. Chemistry. |
발행사항 | [S.l.]: Purdue University., 2018. |
발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2018. |
형태사항 | 241 p. |
기본자료 저록 | Dissertation Abstracts International 80-01B(E). Dissertation Abstract International |
ISBN | 9780438359970 |
학위논문주기 | Thesis (Ph.D.)--Purdue University, 2018. |
일반주기 |
Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
Adviser: Christopher H. Uyeda. |
요약 | Imido complexes are a class of organometallic compounds composed of a metal bonded with a divalent nitrogen ligand. Monometallic imido complexes have been shown to engage in a variety of chemical transformations such as two-electron group transf |
요약 | In contrast to monometallic imido species, the chemistry of bimetallic bridging imido complexes is much less understood. Although bridging dinuclear imido complexes have been isolated, the reported reactivity of these species is limited compared |
요약 | In this work we demonstrate that bridging imido complexes can exhibit chemistry that is just as rich as, and in many cases orthogonal to, that of monometallic imidos. The content of this thesis will begin with a discussion of metal--metal bonds |
일반주제명 | Inorganic chemistry. |
언어 | 영어 |
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