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Diverse Reactivity of Bimetallic Nickel Imido Complexes Supported by a Redox-active Ligand

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서명/저자사항Diverse Reactivity of Bimetallic Nickel Imido Complexes Supported by a Redox-active Ligand.
개인저자Powers, Ian G.
단체저자명Purdue University. Chemistry.
발행사항[S.l.]: Purdue University., 2018.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2018.
형태사항241 p.
기본자료 저록Dissertation Abstracts International 80-01B(E).
Dissertation Abstract International
ISBN9780438359970
학위논문주기Thesis (Ph.D.)--Purdue University, 2018.
일반주기 Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
Adviser: Christopher H. Uyeda.
요약Imido complexes are a class of organometallic compounds composed of a metal bonded with a divalent nitrogen ligand. Monometallic imido complexes have been shown to engage in a variety of chemical transformations such as two-electron group transf
요약In contrast to monometallic imido species, the chemistry of bimetallic bridging imido complexes is much less understood. Although bridging dinuclear imido complexes have been isolated, the reported reactivity of these species is limited compared
요약In this work we demonstrate that bridging imido complexes can exhibit chemistry that is just as rich as, and in many cases orthogonal to, that of monometallic imidos. The content of this thesis will begin with a discussion of metal--metal bonds
일반주제명Inorganic chemistry.
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