자료유형 | 학위논문 |
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서명/저자사항 | Gas-Phase and Condensed-Phase Studies of Small Reactive Intermediates. |
개인저자 | Haskins, Chris William. |
단체저자명 | Purdue University. Chemistry. |
발행사항 | [S.l.]: Purdue University., 2018. |
발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2018. |
형태사항 | 147 p. |
기본자료 저록 | Dissertation Abstracts International 80-01B(E). Dissertation Abstract International |
ISBN | 9780438369078 |
학위논문주기 | Thesis (Ph.D.)--Purdue University, 2018. |
일반주기 |
Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
Adviser: Paul G. Wenthold. |
요약 | Nitriles are an integral functional group in many chemical industries. A new methodology for the dehydration of amides to nitriles has been developed using a palladium catalyst. The reaction conditions are robust and able to tolerate a wide var |
요약 | Cyclopropanols are important precursors for the generation of beta-carbonyl radicals. In the presence of a single-electron oxidant, the beta-carbonyl radical can be generated and trapped. In this methodology, N-aryl acrylamides were used as a tr |
요약 | Aryl Nitrenes are the other reactive intermediates of interest. Although extensively studied over the past 30 years, phenylnitrenes have a propensity for undergoing rearrangement reactions and forming polymeric tars. This is in direct contrast w |
일반주제명 | Organic chemistry. |
언어 | 영어 |
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