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Thermal Rearrangement Reactions of Polyynes and Preparation of Bio-renewable Monomers and Their Polymerizations
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| 자료유형 | 학위논문 |
|---|---|
| 서명/저자사항 | Thermal Rearrangement Reactions of Polyynes and Preparation of Bio-renewable Monomers and Their Polymerizations. |
| 개인저자 | Wang, Yuanxian. |
| 단체저자명 | University of Minnesota. Chemistry. |
| 발행사항 | [S.l.]: University of Minnesota., 2018. |
| 발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2018. |
| 형태사항 | 297 p. |
| 기본자료 저록 | Dissertation Abstracts International 80-01B(E). Dissertation Abstract International |
| ISBN | 9780438351301 |
| 학위논문주기 | Thesis (Ph.D.)--University of Minnesota, 2018. |
| 일반주기 |
Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
Adviser: Thomas R. Hoye. |
| 요약 | Part I: This study explored several novel features of the hexadehydro-Diels-Alder (HDDA) reaction of substrates containing tethered trapping moieties. Three aspects are estiblished experimentally: i) Medium-sized fused rings can be produced by v |
| 요약 | Part II: An unprecedented rearrangement reaction of alkynyl ynedione substrate is discovered, and the product of this process is butenolide-type compounds. The mechanism of this process has been thoroughly studied by both experimental and comput |
| 요약 | Part III: The first conversion of alpha-methyleneglutaric anhydride to (a series of) alpha- methyleneglutarimides has been realized. These potentially bio-renewable monomers can then be polymerized to the corresponding polymers. These polymeric |
| 요약 | Part IV: A ketolactone monomer has been made from bio-sourced levulinic acid via a simple and scalable process. The polymerization reaction of this monomer gives a novel class of polyester and the polyester showed a series of promising propertie |
| 일반주제명 | Chemistry. Organic chemistry. Polymer chemistry. |
| 언어 | 영어 |
| 바로가기 | 
: 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
