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Chemical Thermodynamics of Water Soluble Organic Compounds Found in Aqueous Atmospheric Aerosols: Modeling and Microfluidic Measurements

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서명/저자사항Chemical Thermodynamics of Water Soluble Organic Compounds Found in Aqueous Atmospheric Aerosols: Modeling and Microfluidic Measurements.
개인저자Nandy, Lucy.
단체저자명University of Minnesota. Mechanical Engineering.
발행사항[S.l.]: University of Minnesota., 2018.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2018.
형태사항334 p.
기본자료 저록Dissertation Abstracts International 80-01B(E).
Dissertation Abstract International
ISBN9780438351349
학위논문주기Thesis (Ph.D.)--University of Minnesota, 2018.
일반주기 Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
Adviser: Cari S. Dutcher.
요약Atmospheric aerosols, suspensions of tiny particulates in atmosphere, are known to have a major impact on Earth's climate. Due to the highly chemically and physically complex nature of aerosol particles, large uncertainty in climate modeling ari
요약The specific objectives attained in this dissertation research are as follows.
요약I. Aqueous Solution Thermodynamic Model Development: Thermodynamic analytic predictive models using statistical mechanics were developed for multicomponent systems across the entire range of equilibrium relative humidity (RH - 0 to 100%). The mo
요약II. Model Applications: (1) pH of aerosols was evaluated in a collaborative work, which is of significant interest due to its effect on the environment. (2) Hygroscopicity was estimated in a collaborative work, which has effects on the optical p
요약III. Experimental Microfluidics: The thermodynamic model was parameterized and validated with measurements of water uptake of multicomponent aerosol particles. The influence of relative humidity on phase behavior to assess the effects on water l
요약The efforts in this dissertation together will enhance understanding of atmospheric aerosol phase, solid/liquid/gas partitioning, and liquid-liquid morphologies found in the troposphere. Additionally, the measurements and modeling performed here
일반주제명Mechanical engineering.
Atmospheric chemistry.
Chemical engineering.
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