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Applications of Boron in Iridium, Copper, and Nickel Catalysis

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서명/저자사항Applications of Boron in Iridium, Copper, and Nickel Catalysis.
개인저자Tobolowsky, Robert.
단체저자명University of California, Los Angeles. Chemistry.
발행사항[S.l.]: University of California, Los Angeles., 2018.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2018.
형태사항327 p.
기본자료 저록Dissertation Abstracts International 79-12B(E).
Dissertation Abstract International
ISBN9780438173026
학위논문주기Thesis (Ph.D.)--University of California, Los Angeles, 2018.
일반주기 Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
Adviser: Craig A. Merlic.
요약A method is reported for synthesis of synthetically-valuable borylated pyridines via a Lewis acid promoted C-H activation approach. The transformation involves BF3 or BH3 Lewis-acid precomplexation followed by Ir-catalyzed borylation. The method
요약The synthesis and screening of various pi-base ligands for use in a copper-promoted coupling reaction of alcohols and vinyl boronates are also highlighted. While alkenes and alkynes are frequently used as pi-bond ligands in transition-metal prom
요약Next, building upon our previous work on palladium-catalyzed oxidative couplings of vinyl boronates, we describe our efforts towards translating this chemistry to a nickel-catalyzed manifold. Central to the success of this new method was the ser
요약The final part of this work chronicles the design and synthesis of a new class of carbon-monoxide releasing molecules. While carbon monoxide is a pervasive environmental toxin, it's also an endogenously-produced, essential signaling molecule in
일반주제명Organic chemistry.
Chemistry.
언어영어
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