자료유형 | 학위논문 |
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서명/저자사항 | Applications of Boron in Iridium, Copper, and Nickel Catalysis. |
개인저자 | Tobolowsky, Robert. |
단체저자명 | University of California, Los Angeles. Chemistry. |
발행사항 | [S.l.]: University of California, Los Angeles., 2018. |
발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2018. |
형태사항 | 327 p. |
기본자료 저록 | Dissertation Abstracts International 79-12B(E). Dissertation Abstract International |
ISBN | 9780438173026 |
학위논문주기 | Thesis (Ph.D.)--University of California, Los Angeles, 2018. |
일반주기 |
Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
Adviser: Craig A. Merlic. |
요약 | A method is reported for synthesis of synthetically-valuable borylated pyridines via a Lewis acid promoted C-H activation approach. The transformation involves BF3 or BH3 Lewis-acid precomplexation followed by Ir-catalyzed borylation. The method |
요약 | The synthesis and screening of various pi-base ligands for use in a copper-promoted coupling reaction of alcohols and vinyl boronates are also highlighted. While alkenes and alkynes are frequently used as pi-bond ligands in transition-metal prom |
요약 | Next, building upon our previous work on palladium-catalyzed oxidative couplings of vinyl boronates, we describe our efforts towards translating this chemistry to a nickel-catalyzed manifold. Central to the success of this new method was the ser |
요약 | The final part of this work chronicles the design and synthesis of a new class of carbon-monoxide releasing molecules. While carbon monoxide is a pervasive environmental toxin, it's also an endogenously-produced, essential signaling molecule in |
일반주제명 | Organic chemistry. Chemistry. |
언어 | 영어 |
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