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Corrosion of Copper in Deaerated Deionized Water and Geometry Induced Frequency Dispersion of the Ring Electrode

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서명/저자사항Corrosion of Copper in Deaerated Deionized Water and Geometry Induced Frequency Dispersion of the Ring Electrode.
개인저자Cleveland, Christopher N.
단체저자명University of Florida. Chemical Engineering.
발행사항[S.l.]: University of Florida., 2017.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2017.
형태사항111 p.
기본자료 저록Dissertation Abstracts International 79-12B(E).
Dissertation Abstract International
ISBN9780438165670
학위논문주기Thesis (Ph.D.)--University of Florida, 2017.
일반주기 Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
요약Copper is commonly regarded to be immune to corrosion in deaerated deionized electrolytes. The present work shows that, in the absence of hydrogen, copper will corrode on the order of 1 nm/day in deionized water with an O2 concentration on the o
요약An extended kinetic model is developed and used to study the cumulative corrosion rate of copper after 15 years for a microelectrode and for bulk copper. The parameters varied for this study were the area to volume ratio, copper and hydrogen mas
요약Simulations performed using a refined kinetic model for a microelectrode, validate the assumption that the hydrogen oxidation reaction can be neglected for the small electrode area to volume ratio and short times considered. The hydrogen oxidati
요약A 2-D axisymmetric mathematical model was developed to investigate frequency dispersion in a ring electrode. The finite element software COMSOL Multiphysics was used to solve Laplace's equation in cylindrical coordinates for the ring electrode w
일반주제명Chemical engineering.
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