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Photo-Induced Electron and Energy Transfer in Donor-Acceptor Systems Featuring a Spin-Coupled Metal Dimer

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서명/저자사항Photo-Induced Electron and Energy Transfer in Donor-Acceptor Systems Featuring a Spin-Coupled Metal Dimer.
개인저자Arias-Rotondo, Daniela Mariana.
단체저자명Michigan State University. Chemistry - Doctor of Philosophy.
발행사항[S.l.]: Michigan State University., 2018.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2018.
형태사항351 p.
기본자료 저록Dissertation Abstracts International 79-10B(E).
Dissertation Abstract International
ISBN9780438016323
학위논문주기Thesis (Ph.D.)--Michigan State University, 2018.
일반주기 Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
Adviser: James K. McCusker.
요약Molecular species containing two or more paramagnetic centers in close proximity may exhibit properties that are distinct from those of the individual centers. In these spin-coupled systems, the spin exchange interaction creates an array of new
요약Previous work in our group has suggested a connection between the strength of spin exchange and the rate constant for bimolecular electron transfer. To circumvent the problems inherent to bimolecular systems (diffusion-limited kinetics, poorly d
요약In this dissertation, the synthesis and characterization of several D-A systems are discussed
요약The major drawback of the synthetic design used to prepare the D-A systems studied in this work is their lability, which in some cases led to rapid decomposition of the assemblies in solution. Synthetic efforts to build more robust D-A complexes
일반주제명Inorganic chemistry.
Physical chemistry.
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