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Synthesis and Reactivity of Paramagnetic Late Transition Metal Complexes Supported by Tris(Oxazolinyl)Phenylborate
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| 자료유형 | 학위논문 |
|---|---|
| 서명/저자사항 | Synthesis and Reactivity of Paramagnetic Late Transition Metal Complexes Supported by Tris(Oxazolinyl)Phenylborate. |
| 개인저자 | Reinig, Regina Rose. |
| 단체저자명 | Iowa State University. Chemistry. |
| 발행사항 | [S.l.]: Iowa State University., 2018. |
| 발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2018. |
| 형태사항 | 156 p. |
| 기본자료 저록 | Dissertation Abstracts International 79-11B(E). Dissertation Abstract International |
| ISBN | 9780438076877 |
| 학위논문주기 | Thesis (Ph.D.)--Iowa State University, 2018. |
| 일반주기 |
Source: Dissertation Abstracts International, Volume: 79-11(E), Section: B.
Adviser: Aaron D. Sadow. |
| 요약 | Our group previously developed the synthesis of main group Zn(II) and Mg(II) complexes supported by the ToM (tris(4,4-dimethyl-2-oxazolinyl)phenylborate) ligand. The reactivity of these main group oxazolinyl based complexes in oxygenation, hydro |
| 요약 | Salt metathesis reaction of TlToM with CoCl2&bull |
| 요약 | Reaction of ToMCoCl, ToMFeBr, and To MNiCl with alkyllithiums or potassium benzyl were attempted as a route to organometallic complexes. The nickel(II) alkyls were not identified under the reaction conditions attempted |
| 요약 | ToMCoR (R = Me, Et, nBu, CH2SiMe3, Bn, and Ph) complexes react with CO followed by O2 to form the carboxylate compounds ToMCoO2CR (R = Me, Et, nBu, CH2SiMe3, Bn, and Ph). The direct insertion of CO 2 into the Co-R bond is determined to be much s |
| 일반주제명 | Inorganic chemistry. |
| 언어 | 영어 |
| 바로가기 | 
: 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
