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Mechanism and Application of a Heterogeneous Catalytic Hydrogen-deuterium Exchange Reaction for Polyolefins

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서명/저자사항Mechanism and Application of a Heterogeneous Catalytic Hydrogen-deuterium Exchange Reaction for Polyolefins.
개인저자Zeng, Yiming.
단체저자명University of Minnesota. Chemical Engineering.
발행사항[S.l.]: University of Minnesota., 2018.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2018.
형태사항152 p.
기본자료 저록Dissertation Abstracts International 79-10B(E).
Dissertation Abstract International
ISBN9780438031661
학위논문주기Thesis (Ph.D.)--University of Minnesota, 2018.
일반주기 Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
Advisers: Frank S. Bates
요약The mechanism of a heterogeneous catalytic H/D exchange reaction with polyolefins is investigated in this thesis. The model polymers used in this study were hydrogenated polybutadienes (hPBDs), and a metallocene linear low density polyethylene (
요약In this thesis, several aspects of the isotope exchange reaction were investigated. We first examined the dependence of the isotope exchange on the molecular weight and branch content of the substrate polyolefins. The extent of isotope exchange
일반주제명Physics.
Chemical engineering.
Polymer chemistry.
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