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Synthetically Guided Investigation of Lanthanide and Actinide Redox and Bonding Properties
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| 자료유형 | 학위논문 |
|---|---|
| 서명/저자사항 | Synthetically Guided Investigation of Lanthanide and Actinide Redox and Bonding Properties. |
| 개인저자 | Pattenaude, Scott A. |
| 단체저자명 | Purdue University. Chemistry. |
| 발행사항 | [S.l.]: Purdue University., 2018. |
| 발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2018. |
| 형태사항 | 185 p. |
| 기본자료 저록 | Dissertation Abstracts International 79-10B(E). Dissertation Abstract International |
| ISBN | 9780438018570 |
| 학위논문주기 | Thesis (Ph.D.)--Purdue University, 2018. |
| 일반주기 |
Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
Adviser: Suzanne C. Bart. |
| 요약 | The complex bonding and redox properties of actinide elements are much less understood compared to common main group and transition metal elements. This is likely the result of fewer chemical studies, due to the challenges of working with these |
| 요약 | Along these lines, the first chapter discusses the interactions of an ONO-chelating redox-active ligand with uranium. Uranium derivatives of a dioxophenoxazine ligand, (DOPOq)2UO2, (DOPOsq)UI 2(THF)2, (DOPOcat)UI(THF)2, and Cp*U(DOPOcat)(THF)2 ( |
| 요약 | The second chapter describes the stability imparted by this dioxophenoxazine ligand in the formation of tris(DOPO) complexes. This chapter involves the discussion of the first non-aqueous isostructural series of coordination compounds for member |
| 요약 | The third chapter addresses subtle electronic characteristics associated with redox-active ligand uranium complexes. Uranium complexes (Mes DAE)2U(THF) (1-DAE) and Cp2U( MesDAE) (2-DAE), bearing redox-innocent alpha-diamine ligands, have been sy |
| 요약 | The fourth chapter describes the synthesis of redox-active pyridine(diimine) (PDI) lanthanide complexes with an aim to bring redox activity to the notoriously redox non active metal centers. A full reduction series of the Mes PDIMe ligated to ne |
| 요약 | The fifth chapter describes the synthesis and reactivity of new uranyl complexes containing novel alkyl amide ligands. New uranyl derivatives featuring the amide ligand, -N(SiHMe2)tBu, were synthesized and characterized by X-ray crystallography, |
| 일반주제명 | Chemistry. Inorganic chemistry. |
| 언어 | 영어 |
| 바로가기 | 
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