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Expanding the Structural Scope of Supramolecular Assemblies and Their Applications as Mechanistic Probes
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| 자료유형 | 학위논문 |
|---|---|
| 서명/저자사항 | Expanding the Structural Scope of Supramolecular Assemblies and Their Applications as Mechanistic Probes. |
| 개인저자 | Hong, Cynthia Marilyn. |
| 단체저자명 | University of California, Berkeley. Chemistry. |
| 발행사항 | [S.l.]: University of California, Berkeley., 2018. |
| 발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2018. |
| 형태사항 | 126 p. |
| 기본자료 저록 | Dissertation Abstracts International 80-01B(E). Dissertation Abstract International |
| ISBN | 9780438324084 |
| 학위논문주기 | Thesis (Ph.D.)--University of California, Berkeley, 2018. |
| 일반주기 |
Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
Advisers: F. Dean Toste |
| 요약 | Chapter 1. A brief background and perspective is provided for the field of supramolecular chemistry. Justification for the continued expansion of the field as well as the work described in this dissertation are presented. |
| 요약 | Chapter 2. A new synthetic strategy for the rapid diversification of M4L6 host structures is described. The outlined approach consists of two components: the first is the late-stage functionalization of a ligand precursor to access structural va |
| 요약 | Chapter 3. A novel supramolecular mechanistic probe is introduced, which serves as an experimental platform for isolating and evaluating the role of host charge in supramolecular catalysis. The probe consists of two isostructural metal--ligand c |
| 요약 | Chapter 4. An unusual enzyme-like mechanism of host--guest binding is described in a new metal--ligand host of Ga4L 4 stoichiometry. The introduction of a sufficiently large and tightly bound guest enforces a configurational isomerization in the |
| 일반주제명 | Chemistry. |
| 언어 | 영어 |
| 바로가기 | 
: 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
