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Rheological Properties of Colloidal and Polymeric Scaffolds Measured Using Multiple Particle Tracking Microrheology

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서명/저자사항Rheological Properties of Colloidal and Polymeric Scaffolds Measured Using Multiple Particle Tracking Microrheology.
개인저자Wehrman, Matthew D.
단체저자명Lehigh University. Chemical Engineering.
발행사항[S.l.]: Lehigh University., 2018.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2018.
형태사항215 p.
기본자료 저록Dissertation Abstracts International 79-10B(E).
Dissertation Abstract International
ISBN9780438058446
학위논문주기Thesis (Ph.D.)--Lehigh University, 2018.
일반주기 Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
Adviser: Kelly M. Schultz.
요약Characterizing the rheological properties of polymeric and colloidal gels during dynamic phase transitions is critical in developing targeted products for industrial and home care use. These materials require specific rheology that allow them to
요약We begin by characterizing the gelation of poly(ethylene glycol) (PEG) hydrogels at varying polymeric interactions and gelation mechanisms. The gels consist of a 20,000 g mol--1 4 arm star PEG backbone end-functionalized with either acrylate or
요약Microrheology is then used to measure the degradation and gelation of a fibrous colloidal gel, hydrogenated castor oil. HCO undergoes a heterogeneous phase transition based on an osmotic pressure gradient, making MPT an ideal measurement tool. T
요약To increase the amount of information gained from MPT experiments, we develop a technique to simultaneously track a bi-disperse population of probe particles. 0.5 and 2.0 microm particles are tracked separately using a brightness based radius of
요약To determine if colloidal rearrangement during phase transition is effecting the scaffold structure of HCO, a micro2rheology, microfluidics with microrheology, is developed. A two-layer microfluidic device is designed to exchange fluid surroundi
요약The effect of shear imparted on the sample during preparation is determined using a combination of microrheology, micro2rheology, and bulk rheology. (Abstract shortened by ProQuest.).
일반주제명Chemical engineering.
Engineering.
언어영어
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