자료유형 | 학위논문 |
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서명/저자사항 | Enantioselective Total Syntheses of Akuammiline Alkaloids and Arynes as Building Blocks for Enantioenriched Products. |
개인저자 | Picazo, Elias. |
단체저자명 | University of California, Los Angeles. Chemistry 0153. |
발행사항 | [S.l.]: University of California, Los Angeles., 2018. |
발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2018. |
형태사항 | 564 p. |
기본자료 저록 | Dissertation Abstracts International 79-10B(E). Dissertation Abstract International |
ISBN | 9780438037939 |
학위논문주기 | Thesis (Ph.D.)--University of California, Los Angeles, 2018. |
일반주기 |
Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
Adviser: Neil K. Garg. |
요약 | This dissertation features two projects concerning natural product synthesis and reaction development. The importance of natural product synthesis in chemistry and medicine cannot be overstated. In addition to providing a complex setting to test |
요약 | Chapters One, Two, Three, and Four focus on an unusual variant of the Fischer indolization reaction and its application in the total synthesis of a particularly interesting class of indole alkaloids named the akuammilines. Specifically, Chapter |
요약 | Chapters Two, Three, and Four describe enantioselective syntheses of various akuammiline alkaloids, in addition to several akuammiline alkaloid derivatives. Central to our approach was the development of modern variants of the classic Fischer in |
요약 | Chapters Five describes an application of the distortion/interaction model to a variety of mono and disubstituted benzynes and substituted indolynes. Chapter Six is focused on the development of a facile method to synthesize stereodefined quater |
일반주제명 | Organic chemistry. |
언어 | 영어 |
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