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Using Advanced X-Ray Spectroscopic Methods to Probe Actinide 5f Electronic Structure

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서명/저자사항Using Advanced X-Ray Spectroscopic Methods to Probe Actinide 5f Electronic Structure.
개인저자Ditter, Alexander Scott.
단체저자명University of Washington. Physics.
발행사항[S.l.]: University of Washington., 2019.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2019.
형태사항300 p.
기본자료 저록Dissertations Abstracts International 81-04B.
Dissertation Abstract International
ISBN9781088329368
학위논문주기Thesis (Ph.D.)--University of Washington, 2019.
일반주기 Source: Dissertations Abstracts International, Volume: 81-04, Section: B.
Advisor: Seidler, Gerald T.
이용제한사항This item must not be sold to any third party vendors.This item must not be added to any third party search indexes.
요약X-ray absorption spectroscopy (XAS) and x-ray emission spectroscopy (XES) are element specific, bulk sensitive measures of local electronic structure. As such, they make an ideal probe of actinide 5f electrons, and are situated to answer important questions about actinide covalency. To this end, I have performed resonant inelastic x-ray scattering measurements on uranium 4+ and 5+ hexachlorides to show that UVCl61- is the more covalent of the two compounds due to the energy degeneracy between the uranium and chlorine atomic orbitals. Also discussed here is the work I did to make these measurements possible using a compact, dispersive Rowland circle monochromator at the Stanford Synchrotron Radiation Lightsource. I also discuss my contributions to the goal of expanding access to XAS and XES, and in particular the development of the Clean Energy Institute X-ray Absorption Near-Edge Spectrometer, CEI-XANES, where I lead a project to create the world's first modern laboratory mail-in XAS user facility.
일반주제명Condensed matter physics.
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