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N,N-Diaryl Dihydrophenazine Photoredox Catalysis for Organocatalyzed Atom Transfer Radical Polymerization
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| 자료유형 | 학위논문 |
|---|---|
| 서명/저자사항 | N,N-Diaryl Dihydrophenazine Photoredox Catalysis for Organocatalyzed Atom Transfer Radical Polymerization. |
| 개인저자 | Ryan, Matthew David. |
| 단체저자명 | Colorado State University. Chemistry. |
| 발행사항 | [S.l.]: Colorado State University., 2019. |
| 발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2019. |
| 형태사항 | 233 p. |
| 기본자료 저록 | Dissertations Abstracts International 81-04B. Dissertation Abstract International |
| ISBN | 9781085797177 |
| 학위논문주기 | Thesis (Ph.D.)--Colorado State University, 2019. |
| 일반주기 |
Source: Dissertations Abstracts International, Volume: 81-04, Section: B.
Advisor: Miyake, Garret M. |
| 이용제한사항 | This item must not be sold to any third party vendors. |
| 요약 | The synthesis, application, and mechanistic investigation of the 5,10-diaryldihydrophenazine catalyst family as applied to organocatalyzed atom transfer radical polymerization is presented in this dissertation. The N,N-Diaryl Dihydrophenazine catalyst family, which will be referred to in this dissertation as the phenazines, are an appealing class of molecules due to their strongly reducing excited states, accessed through modular syntheses enabling a wide range of photophysical and electrochemical properties. This class of molecules represented the first example of organic catalysts capable of operating a controlled, visible light driven, organocatalyzed atom transfer radical polymerization for the precision syntheses of (meth)acrylic polymers. Phenazine catalysts were shown to polymerize (meth)acrylic monomers to polymers of very low dispersities (< 1.10) in a process with quantitative initiator efficiency |
| 일반주제명 | Chemistry. Polymer chemistry. |
| 언어 | 영어 |
| 바로가기 | 
: 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
