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The Exploration and Development of Iron-Based Catalysts for the Synthesis of Commodity Polymers
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| 자료유형 | 학위논문 |
|---|---|
| 서명/저자사항 | The Exploration and Development of Iron-Based Catalysts for the Synthesis of Commodity Polymers. |
| 개인저자 | Kehl, Jeffrey Allan, II. |
| 단체저자명 | Boston College. GSAS - Chemistry. |
| 발행사항 | [S.l.]: Boston College., 2019. |
| 발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2019. |
| 형태사항 | 355 p. |
| 기본자료 저록 | Dissertations Abstracts International 81-05B. Dissertation Abstract International |
| ISBN | 9781088379875 |
| 학위논문주기 | Thesis (Ph.D.)--Boston College, 2019. |
| 일반주기 |
Source: Dissertations Abstracts International, Volume: 81-05, Section: B.
Advisor: Byers, Jeffery A. |
| 이용제한사항 | This item must not be sold to any third party vendors. |
| 요약 | This dissertation focuses on the development of iron-based polymerization catalysts for use in the production of high commodity polymers, polyethylene and poly(lactic acid). Chapter one establishes the current landscape of the plastic market and outlines the advantages to developing iron-based catalysts. Chapter two then explores the use of bis(pyridinylimino)isoindolate-ligated iron complexes as a family of ethylene polymerization catalysts possessing distinctive mechanistic behavior. Chapter three moves to focus on the polymerization of stereoregular poly(lactic acid) from an achiral bis(imino)pyridine-ligated iron precatalyst. The mechanism for the desymmetrization of the catalyst is further detailed, and new avenues for enhancing the behavior of the reaction are discussed. Chapter four details the development of conditions for the rapid chain transfer polymerization of lactide and cyclohexene oxide, offering another tool by which value and complexity may be added to polymerization reactions carried out by this family of bis(imino)pyridine-ligated iron complexes. Finally, chapter five leverages the known redox-switchable features of bis(imino)pyridine-ligated iron complexes to develop reaction conditions for the controlled branching of poly(lactic acid) in a one-pot polymerization reaction. |
| 일반주제명 | Chemistry. Polymer chemistry. Plastics. |
| 언어 | 영어 |
| 바로가기 | 
: 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
