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Conversion of Linkages in Covalent Organic Frameworks
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| 자료유형 | 학위논문 |
|---|---|
| 서명/저자사항 | Conversion of Linkages in Covalent Organic Frameworks. |
| 개인저자 | Waller, Peter J. |
| 단체저자명 | University of California, Berkeley. Chemistry. |
| 발행사항 | [S.l.]: University of California, Berkeley., 2019. |
| 발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2019. |
| 형태사항 | 117 p. |
| 기본자료 저록 | Dissertations Abstracts International 81-04B. Dissertation Abstract International |
| ISBN | 9781085784528 |
| 학위논문주기 | Thesis (Ph.D.)--University of California, Berkeley, 2019. |
| 일반주기 |
Source: Dissertations Abstracts International, Volume: 81-04, Section: B.
Advisor: Yaghi, Omar M. |
| 이용제한사항 | This item must not be sold to any third party vendors.This item must not be added to any third party search indexes. |
| 요약 | Chapter 1: Linking small organic molecules into an extended solid typically generates amorphous, disordered polymer. The introduction of order into such a material is of interest because it allows for fine control of the overall structure. Covalent Organic Frameworks (COFs) represent a solution to this problem. They are a new class of porous highly crystalline solids formed by combining organic precursors into an extended structure. Notably, the judicious choice of linkers can give rise to highly regular and predictable materials. Much research is directed toward the development of new methods of linking building blocks together to generate crystalline COFs. These efforts promise not only new materials, but also the chance to extend the principles of molecular covalent chemistry to the formation of organic crystals.Chapter 2: The formation of a COF linked through carbon-carbon bonds is targeted via the Diels-Alder reaction between furan and maleimide. This reaction was chosen since it is thermally reversible, allowing for error correction and therefore, the synthesis of crystalline material. This material would constitute the first example of a COF linked by carbon-carbon bonds. However, these efforts were not rewarded with success |
| 일반주제명 | Organic chemistry. Materials science. |
| 언어 | 영어 |
| 바로가기 | 
: 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
