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Electrostatically Enhanced Thioureas: Synthesis, Reactivity and Selectivity

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서명/저자사항Electrostatically Enhanced Thioureas: Synthesis, Reactivity and Selectivity.
개인저자Fan, Yang.
단체저자명University of Minnesota. Chemistry.
발행사항[S.l.]: University of Minnesota., 2018.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2018.
형태사항207 p.
기본자료 저록Dissertation Abstracts International 80-01B(E).
Dissertation Abstract International
ISBN9780438353596
학위논문주기Thesis (Ph.D.)--University of Minnesota, 2018.
일반주기 Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
Adviser: Steven R. Kass.
요약Hydrogen bonding exhibits its importance in enzyme-catalyzed chemical transformations, naturally occurring three-dimensional architectures and molecular recognition. In recent years, synthetic chemists have successfully exploited hydrogen bonds
요약Thiourea derivatives are among the most common and widely-developed hydrogen bond catalysts. Impressive results in terms of both yields and enantioselectivities in asymmetric syntheses have been obtained. A key feature in their success is the ab
요약The work described in this thesis focuses on the development of a class of positively charged acidity-enhanced thiourea catalysts which make use of an alkylated pyridinium substituent and an appropriate non-coordinating counteranion to enhance t
일반주제명Chemistry.
Organic chemistry.
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