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Efforts Toward Catalytic Methods Based on P(III)/P(V) Redox Cycling
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| 자료유형 | 학위논문 |
|---|---|
| 서명/저자사항 | Efforts Toward Catalytic Methods Based on P(III)/P(V) Redox Cycling. |
| 개인저자 | Zhao, Wei. |
| 단체저자명 | The Pennsylvania State University. Chemistry. |
| 발행사항 | [S.l.]: The Pennsylvania State University., 2016. |
| 발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2016. |
| 형태사항 | 341 p. |
| 기본자료 저록 | Dissertation Abstracts International 79-12B(E). Dissertation Abstract International |
| ISBN | 9780438136229 |
| 학위논문주기 | Thesis (Ph.D.)--The Pennsylvania State University, 2016. |
| 일반주기 |
Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
|
| 요약 | This dissertation describes efforts in the development of catalytic methods that are based on P(III)/P(V) redox cycling. Specifically, a catalytic oxygen atom transfer operating on P(III)/P(V)=O redox cycling and a reversible strong bond activat |
| 요약 | Part I of the dissertation is focused on the development of a new type of phosphorus(III)-mediated carbonyl functionalization via the condensation of electron-deficient carbonyl compounds and nucleophilic trivalent phosphorus compounds (aka the |
| 요약 | Part II of the dissertation extends the study on the effect of molecular geometry on reactivity. Through the design and synthesis of a new type of bicyclic phosphorous triamides with lower symmetry than canonical trivalent phosphorus compounds, |
| 요약 | In pursuing catalysis based on P(III)/P(V) redox cycling, we have illustrated the power of alternating reactivity via manipulating molecular geometry on both kinetic and thermodynamic terms. The strategy of molecular geometric distortion in the |
| 일반주제명 | Chemistry. Inorganic chemistry. Organic chemistry. |
| 언어 | 영어 |
| 바로가기 | 
: 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
