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Synthesis and Reactivity of Highly Stabilized Cyclopentadienes
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| 자료유형 | 학위논문 |
|---|---|
| 서명/저자사항 | Synthesis and Reactivity of Highly Stabilized Cyclopentadienes. |
| 개인저자 | Radtke, Mark Alexander. |
| 단체저자명 | Columbia University. Chemistry. |
| 발행사항 | [S.l.]: Columbia University., 2018. |
| 발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2018. |
| 형태사항 | 164 p. |
| 기본자료 저록 | Dissertation Abstracts International 80-02B(E). Dissertation Abstract International |
| ISBN | 9780438384545 |
| 학위논문주기 | Thesis (Ph.D.)--Columbia University, 2018. |
| 일반주기 |
Source: Dissertation Abstracts International, Volume: 80-02(E), Section: B.
Adviser: Tristan H. Lambert. |
| 요약 | This dissertation focuses on the development of cyclopentadienes as an emerging class of compounds for use in catalysis. Previous work in the Lambert group had established pentacarboxycyclopentadienes (PCCPs) as a promising class of Bronsted aci |
| 요약 | Initial efforts were focused on the synthesis of leading to the development of two complementary methods for their synthesis. Chapter 2 details the improvements made to the transesterification of penta(methoxycarbonyl)cyclopentadiene, which allo |
| 요약 | The second half of the dissertation examines the use of electrophilic silicon reagents and their use as Lewis acids. Given our ability to access highly electron-deficient cyclopentadienes, the silyl cyclopentadienes were targeted as potential Le |
| 일반주제명 | Organic chemistry. Chemistry. |
| 언어 | 영어 |
| 바로가기 | 
: 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
