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The Electronic and Atomic Structure of Actinide Contaminants at the Mineral-Fluid Interface

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서명/저자사항The Electronic and Atomic Structure of Actinide Contaminants at the Mineral-Fluid Interface.
개인저자Gebarski, Benjamin Bartholomew.
단체저자명University of Michigan. Earth and Environmental Sciences.
발행사항[S.l.]: University of Michigan., 2018.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2018.
형태사항175 p.
기본자료 저록Dissertation Abstracts International 79-12B(E).
Dissertation Abstract International
ISBN9780438126848
학위논문주기Thesis (Ph.D.)--University of Michigan, 2018.
일반주기 Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
Adviser: Udo Becker.
요약Geochemical reactions at the mineral-water interface are a critical factor in the mobility of actinide contaminants such as those intrinsic to nuclear waste storage facilities. Actinides can undergo a number of sorption, phase, and oxidation sta
요약In reducing conditions, soluble uranyl(VI) (UO22+) can be reduced to insoluble U(IV)O2 solid, resulting in the decrease of its mobility within the environment. Chapter 2 is an electrochemical investigation of U(VI) redox interactions in a relati
요약Actinide contaminants such as uranyl peroxides can also be immobilized via redox or adsorption reactions catalyzed by mineral surfaces. Therefore Chapter 3 uses electrochemical atomic force microscopy (EC-AFM) in conjunction with spectroscopic m
요약Actinides exceptionally mobile in aqueous conditions, such as pentavalent plutonyl (PuO2+), can be immobilized without a change in oxidation state via adsorption or incorporation into mineral hosts. Thus, Chapter 4 is a theoretical investigation
일반주제명Environmental science.
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