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Optimization of Estrogen Analyses and Quantification of Environmental Samples from Pennsylvania Water Systems

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자료유형학위논문
서명/저자사항Optimization of Estrogen Analyses and Quantification of Environmental Samples from Pennsylvania Water Systems.
개인저자Woodward, Emily E.
단체저자명The Pennsylvania State University. Soil Science and Biogeochemistry.
발행사항[S.l.]: The Pennsylvania State University., 2016.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2016.
형태사항188 p.
기본자료 저록Dissertation Abstracts International 79-12B(E).
Dissertation Abstract International
ISBN9780438136113
학위논문주기Thesis (Ph.D.)--The Pennsylvania State University, 2016.
일반주기 Source: Dissertation Abstracts International, Volume: 79-12(E), Section: B.
요약The increase in the presence of pharmaceuticals and endocrine disrupting hormones (EDCs) in the environment has had a direct impact on aquatic organisms in the environment. Estrogen hormones, one class of EDCs, have been quantified in natural so
요약The goals of this dissertation were to (1) determine an optimal estrogen extraction solvent that yielded the largest E1, E2, and EE2 recovery percentages, (2) optimize separation of ten estrogen and estrogenic compounds using different stationar
요약For the first objective, four organic solvents and three solid phase extraction (SPE) loading ratios were evaluated in order to determine an optimal method to extract estrogens from an agricultural soil (1.09 %TOC). Solvents used to extract the
요약For the second objective, standard solutions containing ten estrogenic compounds were separated using six different stationary phase and mobile phase combinations. Three stationary phases were evaluated, C18, biphenyl, and RP-Amide, and two mobi
요약For the third objective, results indicated that sorption varied between E1, E2, and EE2 and between the three soils studied. Partition coefficient values, Kd and Kf, increased with an increase in soil organic carbon concentration and vice versa,
요약Finally, E1, E2, and EE2 baseline data was established for the Penn State Living Filter wastewater irrigation site, and the Sinnemahoning Creek Watershed. At the Living Filter, all three compounds were detected in groundwater well samples. Howev
일반주제명Soil sciences.
Chemistry.
Environmental science.
언어영어
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