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Evaluating the Effects of Anthocyanin Structure and the Role of Metal Ions on the Blue Color Evolution of Anthocyanins in Varied pH Environments

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서명/저자사항Evaluating the Effects of Anthocyanin Structure and the Role of Metal Ions on the Blue Color Evolution of Anthocyanins in Varied pH Environments.
개인저자Sigurdson, Gregory T.
단체저자명The Ohio State University. Food Science and Technology.
발행사항[S.l.]: The Ohio State University., 2016.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2016.
형태사항199 p.
기본자료 저록Dissertation Abstracts International 80-01B(E).
Dissertation Abstract International
ISBN9780438310063
학위논문주기Thesis (Ph.D.)--The Ohio State University, 2016.
일반주기 Source: Dissertation Abstracts International, Volume: 80-01(E), Section: B.
Adviser: M. Monica Giusti.
요약Due to consumer demand and possible health concerns, the use of synthetic food colorants has been decreasing. Synthetic red and yellow colorants are most commonly used in the food industry
요약Acylated and nonacylated derivatives of cyanidin and delphinidin were combined with various metal ions (Mg2+, Al3+, Cr3+, Fe3+, and Ga3+) in factorial excesses to anthocyanin concentration (as large as 2000x [anthocyanin]) in pH 3-8. Phenolic ac
요약Anthocyanin responses to metal ion chelation were dependent on all factors tested. In all pH, anthocyanins exhibited bathochromic and hyperchromic shifts becoming more purple and blue. Largest bathochromic shifts occurred in pH 6, and largest hy
요약Metal chelation resulted in larger bathochromic shifts on anthocyanins with more B-ring hydroxyl groups (delphinidin > cyanidin). Anthocyanins lacking acylation typically underwent much larger bathochromic shifts
요약Bivalent Mg2+ showed no obvious effect on anthocyanin color. Generally, bathochromic shifts on anthocyanin were greatest with more electron rich metal ions: Fe3+ . Ga3+ > Al 3+ > Cr3+.
요약Metal chelation by anthocyanins resulted in blue and purple hues similar to currently used synthetic colorants in pH environments where these colors are not typically expressed, further indicating potential to act as alternatives.
일반주제명Food science.
Organic chemistry.
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