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Leveraging 1,2-Azaborine's Distinct Electronic Structure to Access New Building Blocks
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| 자료유형 | 학위논문 |
|---|---|
| 서명/저자사항 | Leveraging 1,2-Azaborine's Distinct Electronic Structure to Access New Building Blocks. |
| 개인저자 | McConnell, Cameron Reed. |
| 단체저자명 | Boston College. GSAS - Chemistry. |
| 발행사항 | [S.l.]: Boston College., 2019. |
| 발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2019. |
| 형태사항 | 325 p. |
| 기본자료 저록 | Dissertations Abstracts International 81-03B. Dissertation Abstract International |
| ISBN | 9781085679114 |
| 학위논문주기 | Thesis (Ph.D.)--Boston College, 2019. |
| 일반주기 |
Source: Dissertations Abstracts International, Volume: 81-03, Section: B.
Advisor: Liu, Shih-Yuan. |
| 이용제한사항 | This item must not be sold to any third party vendors. |
| 요약 | Described herein are three projects that derive from in-depth studies of the distinct electronic structure of monocyclic 1,2-dihydro-1,2-azaborine (heretofore referred to as simply 1,2-azaborine). In the first chapter, the first comprehensive review of the late-stage functionalization methods available for 1,2-azaborines as well as their bicyclic and polycyclic (BN-PAH) counterparts is presented. In the second chapter, the development of a general method for both C4 and C5 functionalization based on the building block approach is described. The distinct electronic structure of 1,2-azaborine enables the chemical separation and further functionalization of C4 and C5 borylated isomers. In the second part, the C4, C5, and C6 isomers of BN-styrene analogues were prepared using the newly developed azaborine building blocks. The corresponding polymers were synthesized and extensively characterized in order to compare the effects of the BN-bond positioning relative to the polymer chain. In the fourth and final chapter, 1,2-azaborine-containing phosphine ligands featuring a P-B bond are synthesized. A comparative electronic structure analysis is performed between the BN-phosphine ligands and their direct all-carbon counterparts. |
| 일반주제명 | Organic chemistry. |
| 언어 | 영어 |
| 바로가기 | 
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