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Plasmon-assisted Photothermal Catalysis

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서명/저자사항Plasmon-assisted Photothermal Catalysis.
개인저자Barnes, Jena Ariel.
단체저자명Duke University. Mechanical Engineering and Materials Science.
발행사항[S.l.]: Duke University., 2019.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2019.
형태사항148 p.
기본자료 저록Dissertations Abstracts International 81-04B.
Dissertation Abstract International
ISBN9781088333051
학위논문주기Thesis (Ph.D.)--Duke University, 2019.
일반주기 Source: Dissertations Abstracts International, Volume: 81-04, Section: B.
Advisor: Hotz, Nico.
이용제한사항This item must not be sold to any third party vendors.This item must not be added to any third party search indexes.
요약The central objective of this dissertation was to assess the potential use of plasmonic nanostructures in the context of heterogenous catalytic reactions. The research presented in this dissertation was done to specifically examine the production of hydrogen via methanol steam reforming in a more energy-efficient, small-scale manner: through a nanoscale, thermally-driven photocatalytic process. This research specifically explored the use of a plasmonic substrate in order to determine its ability to provide the thermal energy required to drive the methanol steam reforming reaction. In addition, a novel, high-performance Cu-based catalyst for use in the steam reforming reaction was produced and characterized. The effect of the amount of catalyst on the optical properties of the substrate was also explored. Through the use of gas chromatography and a thermodynamic analysis of the reaction process, it was ultimately shown that it is possible to achieve the localized high temperatures that are necessary for the production of hydrogen.
일반주제명Engineering.
Chemical engineering.
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