상세정보
Export to Refworks부가기능
Cross Coupling of Alkenyl Gold Complexes with Alkyl Electrophiles and Nickel Catalyzed Hydroarylation of Alkenes
상세 프로파일
| 자료유형 | 학위논문 |
|---|---|
| 서명/저자사항 | Cross Coupling of Alkenyl Gold Complexes with Alkyl Electrophiles and Nickel Catalyzed Hydroarylation of Alkenes. |
| 개인저자 | Nguyen, Julia. |
| 단체저자명 | University of Washington. Chemistry. |
| 발행사항 | [S.l.]: University of Washington., 2019. |
| 발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2019. |
| 형태사항 | 94 p. |
| 기본자료 저록 | Dissertations Abstracts International 81-04B. Dissertation Abstract International |
| ISBN | 9781088304853 |
| 학위논문주기 | Thesis (Ph.D.)--University of Washington, 2019. |
| 일반주기 |
Source: Dissertations Abstracts International, Volume: 81-04, Section: B.
Advisor: Lalic, Gojko. |
| 이용제한사항 | This item must not be sold to any third party vendors.This item must not be added to any third party search indexes. |
| 요약 | Transition metal catalysis is a powerful strategy for the construction of organic molecules. The development of novel methods in this field can help improve the speed and efficiency with which we synthesize complex organic molecules and broaden the scope of accessible products. Here we describe the development of two reactions involving transition metals. The first is a cross-coupling reaction between alkenyl gold and alkyl triflates, resulting in the formation of a new C-C bond. While several strategies are known that enable 慣-selective cross-coupling of alkenyl gold complexes, we are able to achieve 棺-selective cross-coupling by taking advantage of an alternative mode of reactivity. The second reaction described is a nickel catalyzed hydroarylation of alkenes. We are able to achieve good anti-Markovnikov selectivity with a wide range of alkenes, including styrenes, alkyl substituted alkenes, and enol ethers. |
| 일반주제명 | Chemistry. Metals. Catalysis. Chemical reactions. |
| 언어 | 영어 |
| 바로가기 | 
: 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
