자료유형 | 학위논문 |
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서명/저자사항 | Advancing Frontiers in Reactive and Selective Iridium C-H Borylation Catalysis and Targeted Silsesquioxane Synthesis. |
개인저자 | Dannatt, Jonathan E. |
단체저자명 | Michigan State University. Chemistry - Doctor of Philosophy. |
발행사항 | [S.l.]: Michigan State University., 2019. |
발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2019. |
형태사항 | 521 p. |
기본자료 저록 | Dissertations Abstracts International 81-03B. Dissertation Abstract International |
ISBN | 9781085673259 |
학위논문주기 | Thesis (Ph.D.)--Michigan State University, 2019. |
일반주기 |
Source: Dissertations Abstracts International, Volume: 81-03, Section: B.
Advisor: Maleczka, Rob. |
이용제한사항 | This item must not be sold to any third party vendors. |
요약 | The studies in this dissertation are aimed at uncovering reactive and selective Ir-catalyzed C-H borylation (CHB) catalysts. Due to the high versatility of organoboron species, green methodology to produce the C-B bond is poised to support a myriad of subsequent transformations. These transformations include Suzuki couplings, aminations, oxidations, halogenations, cyanations, and trifluoromethylations.Typical iridium catalyzed CHBs proceed through an iridium trisboryl with a bidentate ligand such as bipyridine or 1,10-phenanthroline. The selectivity of these standard catalysts is generally driven by sterics |
일반주제명 | Organic chemistry. Chemistry. |
언어 | 영어 |
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