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In situ Characterization of Vapor-Deposited Organic Glasses

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서명/저자사항In situ Characterization of Vapor-Deposited Organic Glasses.
개인저자Beasley, Madeleine S.
단체저자명The University of Wisconsin - Madison. Chemistry.
발행사항[S.l.]: The University of Wisconsin - Madison., 2019.
발행사항Ann Arbor: ProQuest Dissertations & Theses, 2019.
형태사항290 p.
기본자료 저록Dissertations Abstracts International 81-04B.
Dissertation Abstract International
ISBN9781687937520
학위논문주기Thesis (Ph.D.)--The University of Wisconsin - Madison, 2019.
일반주기 Source: Dissertations Abstracts International, Volume: 81-04, Section: B.
Advisor: Ediger, Mark.
이용제한사항This item must not be sold to any third party vendors.
요약Vapor-deposited organic glasses are used in a variety of applications, ranging from pharmaceuticals with high bioavailability to the active material for charge mobility in layers of organic light emitting diodes. The glasses studied by the Ediger group are prepared by physical vapor deposition. Depending on the substrate temperature, the as-prepared glasses can have a range of extraordinary properties including high kinetic stability, high density, and suppressed secondary relaxations relative to a glass prepared in the traditional manner of liquid cooling. The work in this thesis focuses on simple organic molecules that serve as model systems for understanding these extraordinary properties that vapor-deposited glasses can have. Specifically, the ability of a series of trialkyl phosphates to form kinetically stable glasses, the proximity of vapor-deposited ethylbenzene glasses to the "ideal glass" state, and physical vapor deposition of the polyamorphic system triphenyl phosphite is described.
일반주제명Chemistry.
Physical chemistry.
언어영어
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