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Selective Synthesis of Aromatic and Saturated Organoboron Compounds
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| 자료유형 | 학위논문 |
|---|---|
| 서명/저자사항 | Selective Synthesis of Aromatic and Saturated Organoboron Compounds. |
| 개인저자 | Shannon, Timothy Michael. |
| 단체저자명 | Michigan State University. Chemistry - Doctor of Philosophy. |
| 발행사항 | [S.l.]: Michigan State University., 2019. |
| 발행사항 | Ann Arbor: ProQuest Dissertations & Theses, 2019. |
| 형태사항 | 300 p. |
| 기본자료 저록 | Dissertations Abstracts International 81-03B. Dissertation Abstract International |
| ISBN | 9781085753609 |
| 학위논문주기 | Thesis (Ph.D.)--Michigan State University, 2019. |
| 일반주기 |
Source: Dissertations Abstracts International, Volume: 81-03, Section: B.
Advisor: Smith, Milton R., III. |
| 이용제한사항 | This item must not be sold to any third party vendors.This item must not be added to any third party search indexes. |
| 요약 | C-H borylation (CHB) is a method to functionalize C-H bonds. The development of CHB has taken many years but is getting to the point of well-established chemistry. The directed CHB is possible for a variety of differing substrates and differing loctions of direction. A new method for ortho directed CHB of esters amides and ketones was developed through the use of pyridine based monodentate ligands.Using 4-cyano-2-methoxypyridine as a ligand iridium catalyzed CHB of esters ketones and amides were performed. The mechanism of CHB in this process likely operates through a different rate-determining step than the other C-H borylation methods used as it was found that the kinetic isotope effect data did not clearly support C-H activation as rate-determining.The development of sp3 C-H borylation is not as advanced as sp2 CHB |
| 일반주제명 | Chemistry. |
| 언어 | 영어 |
| 바로가기 | 
: 이 자료의 원문은 한국교육학술정보원에서 제공합니다. |
